XElement contactXML =
    new XElement("Contact",
        new XElement("Name", "Patrick Hines"),
        new XElement("Phone", "206-555-0144"),
        new XElement("Address",
            new XElement("Street1", "123 Main St"),
            new XElement("City", "Mercer Island"),
            new XElement("State", "WA"),
            new XElement("Postal", "68042")
        )
    );

dynamic contact = new ExpandoObject();
contact.Name = "Patrick Hines";
contact.Phone = "206-555-0144";
contact.Address = new ExpandoObject();
contact.Address.Street = "123 Main St";
contact.Address.City = "Mercer Island";
contact.Address.State = "WA";
contact.Address.Postal = "68402";

dynamic contacts = new List();

contacts.Add(new ExpandoObject());
contacts[0].Name = "Patrick Hines";
contacts[0].Phone = "206-555-0144";

contacts.Add(new ExpandoObject());
contacts[1].Name = "Ellen Adams";
contacts[1].Phone = "206-555-0155";

For more details going here.